New class of meterials offers many benefits

A new class of materials may have the potential of making the current retail gasoline infrastructure compatible with hydrogen-based vehicles of the future — but also contribute to arenas such as nuclear proliferation and global warming. The new material is described in the June issue of The Bulletin, the monthly magazine of the American Ceramic Society. It carries the first news of a never-before-seen class of materials and technology developed by scientists at the Savannah River National Laboratory. This unique material, dubbed Porous Wall-Hollow Glass Microspheres (PW-HGM), consists of porous glass “microballoons” which are smaller than the diameter of a human hair. The key characteristic of these 2-100 micron spheres is an interconnected porosity in their thin outer walls that can be produced and varied on a scale of 100 to 3,000 Angstroms. SRNL Researchers G. G. Wicks, L. K. Heung, and R. F. Schumacher have been able to use these open channels to fill the microballons with gas absorbents and other materials. Hydrogen or other reactive gases can then enter the microspheres through the pores, creating a relatively safe, contained, solid-state storage system. Photographs of these glass-absorbent composites also reveal that the wall porosity generates entirely new nano-structures.

Wicks, Heung, and Schumacher have shown that the PW-HGM’s permeable walls can be used for non-composite purposes, too. For example, the porosity can be altered and controlled in various ways that allow the spheres to filter mixed gas streams within a system. Another feature of the microballoons is that their mechanical properties can be altered so they can be made to flow like a liquid. This suggests that an existing infrastructure that currently transports, stores and distributes liquids such as the existing gasoline distribution and retail network can be used. This property and their relative strength also make the PW-HGMs suitable for reuse and recycling. The SRNL team is involved in more than a half dozen programs and collaborations involving the PW-HGMs in areas such as hydrogen storage in vehicles (Toyota), gas purification and separations, and even very diverse applications including abatement of global warming effects, improving lead-acid battery performance, and nuclear non-proliferation. Applications such as the development of new drug delivery systems and MRI contrast agents are also blossoming in the medical field (Medical College of Georgia).